Chloride induced reinforcement corrosion in concrete is a serious durability problem. Different sources of chloride, i.e. chloride introduced at the fresh stage of concrete (i.e. internal chloride) and chloride entered during the hardened state (i.e. external chloride) may affect the performance of concrete in different ways. For the performance evaluation of reinforced concrete in chloride environment (i.e. both internal and external chloride), there is a need for performing different electrochemical tests to obtain various corrosion parameters that will specify the possibility and the magnitude of corrosion in concrete. In the present study, the results of an experimental investigation that includes different corrosion tests namely potential measurement, corrosion rate measurement and potentiodynamic polarization test have been presented and analyzed to evaluate the performance of concrete both in internal chloride and external chloride exposure conditions. In addition an attempt is made to correlate the corrosion parameters obtained from internal and external chloride exposure conditions. From the results it was observed that, dropped half-cell potential value obtained from external chloride exposure mostly lie in the active zone obtained from internal chloride exposure. In addition it was observed that there was significant difference in corrosion current values obtained from both internal and external chloride exposure conditions. Further on the basis of overall ranking obtained from the results of critical parameters from different exposure conditions, the performance of different cement–steel combinations against chloride induced rebar corrosion has been evaluated. 相似文献
The main goal of this study is to assess and compare three advanced machine learning techniques, namely, kernel logistic regression (KLR), naïve Bayes (NB), and radial basis function network (RBFNetwork) models for landslide susceptibility modeling in Long County, China. First, a total of 171 landslide locations were identified within the study area using historical reports, aerial photographs, and extensive field surveys. All the landslides were randomly separated into two parts with a ratio of 70/30 for training and validation purposes. Second, 12 landslide conditioning factors were prepared for landslide susceptibility modeling, including slope aspect, slope angle, plan curvature, profile curvature, elevation, distance to faults, distance to rivers, distance to roads, lithology, NDVI (normalized difference vegetation index), land use, and rainfall. Third, the correlations between the conditioning factors and the occurrence of landslides were analyzed using normalized frequency ratios. A multicollinearity analysis of the landslide conditioning factors was carried out using tolerances and variance inflation factor (VIF) methods. Feature selection was performed using the chi-squared statistic with a 10-fold cross-validation technique to assess the predictive capabilities of the landslide conditioning factors. Then, the landslide conditioning factors with null predictive ability were excluded in order to optimize the landslide models. Finally, the trained KLR, NB, and RBFNetwork models were used to construct landslide susceptibility maps. The receiver operating characteristics (ROC) curve, the area under the curve (AUC), and several statistical measures, such as accuracy (ACC), F-measure, mean absolute error (MAE), and root mean squared error (RMSE), were used for the assessment, validation, and comparison of the resulting models in order to choose the best model in this study. The validation results show that all three models exhibit reasonably good performance, and the KLR model exhibits the most stable and best performance. The KLR model, which has a success rate of 0.847 and a prediction rate of 0.749, is a promising technique for landslide susceptibility mapping. Given the outcomes of the study, all three models could be used efficiently for landslide susceptibility analysis.
Bioleaching studies for chalcopyrite contained ball mill spillages are very scarce in the literature. We developed a process flow sheet for the recovery of copper metal from surface activated (600 °C, 15 min) ball mill spillage through bio-hydrometallurgical processing route. Bioleaching of the activated sample using a mixed meso-acidophilic bacterial consortium predominantly A. ferrooxidans strains was found to be effective at a lixiviant flow rate of 1.5 L/h, enabling a maximum 72.36% copper recovery in 20 days. Mineralogical as well as morphological changes over the sample surface were seen to trigger the bioleaching efficiency of meso-acidophiles, thereby contributing towards an enhanced copper recovery from the ball mill spillage. The bio-leach liquor containing 1.84 g/L Cu was purified through solvent extraction using LIX 84I in kerosene prior to the recovery of copper metal by electrowinning. Purity of the copper produced through this process was 99.99%. 相似文献
Poly(m-aminophenol) (PmAP) was synthesized by the oxidative polymerization of m-aminophenol in sodium hydroxide medium using ammonium persulfate oxidant at room temperature. The synthesized polymer showed very good solution processability as it was well soluble in aqueous sodium hydroxide, dimethylsulfoxide (DMSO), dymethylformamide (DMF), etc. A free-standing film was cast from thermal evaporation of DMSO solution of the synthesized PmAP. The film was then doped with aqueous sodium hydroxide and methanol mixture by solution doping technique at room temperature. The doping conditions were standardized in terms of the DC-conductivity of the doped film. The doped PmAP was characterized by ultraviolet–visible spectroscopy, Fourier transform infrared spectroscopy, Electron dispersion spectroscopy, X-ray diffraction spectroscopy, elemental analysis by atomic absorption spectroscopy, thermogravimetric analysis and DC-electrical conductivity. The DC-electrical conductivity of PmAP film was increased to 2.34 × 10?5 S/cm from <10?12 S/cm due to sodium ion doping. From all the above characterizations it was confirmed that the sodium ions were not the reason for the conduction. The incorporated sodium cation in the polymer through free –OH groups of the polymer chain was induced the electron cloud of the polymer and so the polymer became conducting. 相似文献
ZnTe quantum dots (QDs) are synthesized at room temperature in a single step by mechanical alloying the stoichiometric equimolar mixture (1:1 mol) of Zn and Te powders under Ar within 1 h of milling. Both XRD and HRTEM characterizations reveal that these QDs having size ∼5 nm contain stacking faults of different kinds. A distinct blue-shift in absorption spectra with decreasing particle size of QDs confirms the quantum size confinement effect (QSCE). It is observed for first time that the QDs with considerable amount of faults can also show the QSCE. Optical band gaps of these QDs increase with increasing milling time and their band gaps can be fine-tuned easily by varying milling time of QDs. 相似文献
X and gamma rays continue to remain the main contributors to the dose to humans. As these photons of varying energies are encountered in various applications, the study of photon energy response of a dosemeter is an important aspect to ensure the accuracy in dose measurement. Responses of dosemeters have to be experimentally established because for luminescence dosemeters, they depend not only on the effective atomic number (ratio of mass energy absorption coefficients of dosemeter and tissue) of the detector, but also considerably on the luminescence efficiency and the material surrounding the dosemeters. Metal filters are generally used for the compensation of energy dependence below 200 keV and/or to provide photon energy discrimination. It is noted that the contribution to Hp(0.07) could be measured more accurately than Hp(10). For the dosemeters exhibiting high photon energy-dependent response, estimation of the beta component of Hp(0.07) becomes very difficult in the mixed field of beta radiation and photons of energy less than 100 keV. Recent studies have shown that the thickness and the atomic number of metal filters not only affect the response below 200 keV but also cause a significant over-response for high energy (>6 MeV) photons often encountered in the environments of pressurised heavy water reactors and accelerators. 相似文献